Sequence-Controlled Polymers Through Entropy-Driven Ring-Opening Metathesis Polymerization: Theory, Molecular Weight Control, and Monomer Design Jamie A. Nowalk, Cheng Fang, Amy L. Short, Ryan M. Weiss, Jordan H. Swisher, Peng Liu, Tara Yvonne … [Continue reading]
Ruthenium-Catalysed Olefin Metathesis in Environmentally Friendly Solvents: 2-Methyltetrahydrofuran Revisited Michał Smoleń, Anna Marczyk, Wioletta Kośnik, Bartosz Trzaskowski, Anna Kajetanowicz,* and Karol Grela* Eur J Org Chem 2019 … [Continue reading]
Selectivity in Ring-Closing Metathesis: Synthesis of Propellanes and Angular Aza-tricycles Sambasivarao Kotha,* Vikas R. Aswar and Saima Ansari Adv Synth Catal 2019 ASAP Influence of Residual Impurities on Ring-Opening Metathesis … [Continue reading]
Asymmetric Total Synthesis of Laurallene Fumihiko Yoshimura,* Taku Okada, and Keiji Tanino* Org Lett 2019 ASAP Synthesis and biological evaluation of fluorinated analogues of ripostatin A Vladyslav Shendermana and Evgeny V. … [Continue reading]
cis-Dichloro Sulfoxide Ligated Ruthenium Metathesis Precatalysts Adam M. Johns,* Bryan A. Fiamengo, Jessica R. Herron, Jean-Baptiste Bourg, Angelino Doppiu, Ralf Karch, and Richard L. Pederson Organometallics 2019 ASAP Looking for the … [Continue reading]
Short Total Synthesis of Δ12-Prostaglandin J2 and Related Prostaglandins. Design, Synthesis and Biological Evaluation of Macrocyclic Δ12-Prostaglandin J2 Analogues K. C. Nicolaou,* Kiran Kumar Pulukuri, Stephan Rigol, Zisis Peitsinis, … [Continue reading]
Concise Asymmetric Synthesis of Kweichowenol A David B. Konrad, Bilal Kicin, Dirk Trauner* Synlett 2018 ASAP ω-Norbornenyl Macromonomers: In Situ Synthesis by End-Capping of Living Anionic Polymers Using a … [Continue reading]
Concise Syntheses of Δ12-Prostaglandin J Natural Products via Stereoretentive Metathesis Jiaming Li, Tonia S. Ahmed, Chen Xu*, Brian M. Stoltz*, and Robert H. Grubbs* J Am Chem Soc 2018 ASAP In Situ Conformational Fixation of the … [Continue reading]
High-Yield Synthesis of a Long-Sought, Labile Ru-NHC Complex and Its Application to the Concise Synthesis of Second-Generation Olefin Metathesis Catalysts Craig S. Day and Deryn E. Fogg* Organometallics 2018 ASAP Influence of Anionic … [Continue reading]
Synthesis of Functionalized Cage Propellanes and D3-Trishomocubanes via the Ring-Closing Metathesis and Acid-Promoted Rearrangement Sambasivarao Kotha,* and Subba Rao Cheekatla Tetrahedron 2018 ASAP Synthetic Studies toward … [Continue reading]
Living Metathesis and Metallotropy Polymerization Gives Conjugated Polyenynes from Multialkynes: How to Design Sequence-Specific Cascades for Polymers Cheol Kang, Seongyeon Kwon, Jong-Chan Sung, Jinwoo Kim, Mu-Hyun Baik,* and Tae-Lim Choi* J Am … [Continue reading]