The Boomerang is Back in Olefin Metathesis


Bates, J. M.; Lummiss, J. A. M.; C.; Bailey; G. A., and Fogg, D. E. “Operation of the Boomerang Mechanism in Olefin Metathesis Reactions Promoted by the Second-Generation Hoveyda Catalyst” ACS Catal., 2014, 4 (7), 2387-94. No consensus has been … [Continue reading]

Olefin Metathesis at the 248th ACS Meeting

The 248th American Chemical Society National Meeting and Exposition will be held in San Francisco, California from August 10-14, 2014. The theme of this fall’s meeting is “Chemistry and Global Stewardship.” As olefin metathesis has made significant … [Continue reading]

Examining Polytopal Rearrangements around Ruthenium


Torker, S.; Khan, R.K.M.; Hoveyda, A.M. “The Influence of Anionic Ligands on Stereoisomerism of Ru Carbenes and Their Importance to Efficiency and Selectivity of Catalytic Olefin Metathesis Reactions” J. Am. Chem. Soc. 2014, 136, 3439-3455. For … [Continue reading]

Olefin Metathesis at the 247th ACS Meeting

The 247th ACS National Meeting and Exposition is less than a month away. The late winter/early spring event is set for Dallas, Texas from March 16-20, 2014. Olefin metathesis has no problem fitting into the meeting’s theme of “Chemistry and Materials … [Continue reading]

Ruthenium Initiators Deliver Syndiotactic Polymers

Figure 1

Keitz, B.K.; Fedorov, A.; Grubbs, R.H. “Cis-Selective Ring-Opening Metathesis Polymerization with Ruthenium Catalysts” J. Am. Chem. Soc. 2012, 134, 2040-2043. Rosebrugh, L.E.; Marx, V.M.; Keitz, B.K.; Grubbs, R.H. “Synthesis of Highly Cis, … [Continue reading]

Olefin Metathesis at 246th ACS Meeting

The American Chemical Society 246th National Meeting & Exhibition will take place this year from Sept 8-12 in Indianapolis, IN. As one might expect, given the location, the theme of the meeting is “Chemistry in Motion.” Although I didn’t see any … [Continue reading]