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ASAP’s – 2020 – Week 33-34

August 21, 2020 By Adam Johns

Nitro and Other Electron Withdrawing Group-Activated Ruthenium Catalysts for Olefin Metathesis Reaction
Anna Kajetanowicz,* and Karol Grela*
Angew Chem Int Ed 2020 ASAP

This review details the development and diverse applications of electron withdrawing group activated Hoveyda-Grubbs type catalysts.


Multigram synthesis of heterabicyclo[n.1.0]alkan-1-yl trifluoroborates
Ihor Kleban, Yevhen Krokhmaliuk, Sofiia Reut, Serhii Shuvakin, Vyacheslav V. Pendyukh, Oleksandr I. Khyzhan, Dmytro S. Yarmoliuk, Dr. Andriy V. Tymtsunik,* Dr. Yuliya V. Rassukana, Dr. Oleksandr O. Grygorenko
Eur J Org Chem 2020 ASAP


ROMP-Boranes as Moisture Tolerant and Recyclable Lewis Acid Organocatalysts
Fernando Vidal, James McQuade, Roger Lalancette, and Frieder Jäkle*
J Am Chem Soc 2020 ASAP


Bicyclohexene-peri-naphthalenes: Scalable Synthesis, Diverse Functionalization, Efficient Polymerization, and Facile Mechanoactivation of Their Polymers
Jinghui Yang, Matias Horst, Sabrina H. Werby, Lynette Cegelski, Noah Z. Burns, Yan Xia*
J Am Chem Soc 2020 ASAP


Ring-Opening Metathesis Polymerization of endo- and exo-Norbornene Lactones
Narumi Miyasako, Shin-ichi Matsuoka,* and Masato Suzuki
Macromol Rapid Comm 2020 ASAP


Adventures and Detours in the Synthesis of Hydropentalenes
Max Deimling, Anna Zens, Natja Park, Christine Hess, Simon Klenk, Zarfishan Dilruba, Angelika Baro, Sabine Laschat*
Synlett 2020 ASAP

Section 8 of this account describes the application of tandem Ring-Opening Metathesis/Ring-Closing Metathesis/Cross-Metathesis for the preparation of fucntionalized hydropentalenes.


Sulfur-Chelated Ruthenium Olefin Metathesis Catalysts
Noy B. Nechmad, N. Gabriel Lemcoff*
Synlett 2020 ASAP

This review from the Lemcoff group summarizes the development and application of sulfur-chelated ruthenium precatalysts.



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