ASAP’s – 2020 – Week 09-12

March 20, 2020 By Adam Johns

Stereoselective Synthesis of Conjugated Polyenes Based on Tethered Olefin Metathesis and Carbonyl Olefination: Application to the Total Synthesis of (+)-Bretonin B
Kajsa Lood and Bernd Schmidt*
J Org Chem 2020 ASAP

A Relay Strategy Actuates Pre-Existing Trisubstituted Olefins in Monoterpenoids for Cross-Metathesis with Trisubstituted Alkenes
Karim A. Bahou, D. Christopher Braddock,* Adam G. Meyer, G. Paul Savage, Zhensheng Shi, and Tianyou He
J Org Chem 2020 ASAP

Hydroxide-Induced Degradation of Olefin Metathesis Catalysts: A Challenge for Metathesis in Alkaline Media
Alexandre Y. Goudreault, Daniel M. Walden, Daniel L. Nascimento, Adrian G. Botti, Stephan N. Steinmann, Carine Michel,* and Deryn E. Fogg*
ACS Catal 2020 ASAP

Olefin Cross Metathesis as a Versatile Method for the Facile Functionalization of Porous Polymers
Amaia Altuna-Ruiz de Eguino, Peter A. G. Cormack,* and Joëlle Prunet*
Org Lett 2020 ASAP

Dewar Heterocycles as Versatile Monomers for Ring-Opening Metathesis Polymerization
Sepand Nistanaki, Hosea Nelson*
ChemRxiv 2020 ASAP

Enantioselective Total Synthesis of (-)-Myrifabral A and B
Tyler J. Fulton, Anthony Chen, Michael Bartberger, Brian Stoltz*
ChemRxiv 2020 ASAP

An additional potential donor-bearing alkylidene containing latent NHC–ruthenium-based catalyst for olefin metathesis polymerization
Dharmalingam Sivanesan, Bongkuk Seo, Choong-Sun Lim, Dongchen Choi, Taehee Kim and Hyeon-Gook Kim*
Polym Chem 2020 ASAP

Polymers from sugars and unsaturated fatty acids: ADMET
polymerisation of monomers derived from D-xylose, D-mannose and castor oil
Marco Piccini, David J. Leak, Christopher J. Chuck, and Antoine Buchard*
Polym Chem 2020 ASAP

Diastereoselective synthesis of trisubstituted olefins using a silicon-tether ring-closing metathesis strategy
Stéphane Wittmann, Alexander F. Tiniakos, and Joëlle Prunet*
Org Biomol Chem 2020 ASAP

Metathesis of norbornene-derivatives bearing trimethylsilyl groups using Ru-alkylidene catalysts: An experimental and computational study
Daniel Zárate-Saldaña, Bruno Landeros-Rivera, Jorge A. Cruz-Morales, Selena Gutiérrez*
J Organomet Chem 2020 ASAP

6,7-Benzotropolone Syntheses Based on Ring-Closing Metatheses and Four-Electron Oxidations
Michael Kreibich, Manuel Gemander, David Peter, Dharmendra B. Yadav, Charles B. de Koning, Manuel A. Fernandes, Ivan R. Green, Willem A. L. van Otterlo,* Reinhard Brückner*
Eur J Org Chem 2020 ASAP

Formal Synthesis of Pseudolaric Acid B
Naoki Mori*
Synlett 2020 ASAP

Stereoselective Total Synthesis of Arundinolides A and B
Caizhu Chang, Jialin Geng, Yinxin Liu, Yuguo Du, Jun Liu,* Zhi-Bing Dong*
Synthesis 2020 ASAP

All Things Metathesis is a blog published by Umicore. For more information, please visit www.pmc.umicore.com

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