All Things Metathesis

ASAP’s – 2019 – Week 47-48

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Synthesis and in vitro biological evaluation of 3-amino-3-deoxydihydrosphingosines and their analogues
Jana Špaková Raschmanová, Miroslava Martinková,* Jozef Gonda, Martina Bago Pilátová, Juraj Kuchár, Dávid Jáger
Tetrahedron 2019 ASAP

Synthesis of Functionalized 6,5- and 7,5-Azabicycloalkane Amino Acids by Metathesis Reactions
Massimo Serra,* Eric Bernardi, Ersilia De Lorenzi, and Lino Colombo
J Org Chem 2019 ASAP

Olefin Metathesis in Confined Geometries: A Biomimetic Approach Towards Selective Macrocyclization
Felix Ziegler, Johannes Teske, Iris Elser, Michael Dyballa, Wolfgang Frey, Hamzeh Kraus, Niels Hansen, Julia Rybka, Ulrich Tallarek, and Michael R Buchmeiser*
J Am Chem Soc 2019 ASAP

Direct synthesis of dialkylarylvinylsilane derivatives: metathesis of dialkylaryl-isopropenylsilane and its application to tetracyclic silacycle dye synthesis
Shohei Yoshioka, Tsunayoshi Takehara, Tsuyoshi Matsuzaki, Takeyuki Suzuki, Hirofumi Tsujino, Tadayuki Uno, Yasuo Tsutsumi, Kenichi Murai, Hiromichi Fujioka and Mitsuhiro Arisawa*
Chem Commun 2019 ASAP

Synthesis and Vitamin D Receptor Affinity of 16-Oxa Vitamin D3 Analogues
Kouta Ibe, Takeshi Yamada, and Sentaro Okamoto*
Org Biomol Chem 2019 ASAP

Synthesis of hyperbranched polyolefins and polyethylenes via ADMET of monomers bearing non-selective olefins
Ning Ren and Xinyuan Zhu*
Polymer Chem 2019 ASAP

A Unified Total Synthesis of the Actinoallolides, a Family of Potent Anti-trypanosomal Macrolides
Matthew J. Anketell, Theodore M. Sharrock and Ian Paterson*
Angew Chem Int Ed 2019 ASAP

Novel benzoquinone- and naphthoquinone-bearing polymers synthesized by ROMP method as cathode materials for lithium-ion batteries
Yeqing Shi, Pengfei Sun, Jixing Yang,* and Yunhua Xu*
ChemSusChem 2019 ASAP

Dewar lactone as a modular platform to a new class of substituted poly(acetylene)s
Jinwon Seo, Stanfield Y. Lee and Christopher W. Bielawski*
Polymer Chem 2019 ASAP

An Unexpected Transannular [4+2] Cycloaddition during the Total Synthesis of (+)-Norcembrene 5
Michael Breunig, Po Yuan, and Tanja Gaich*
Angew Chem Int Ed 2019 ASAP

All Things Metathesis is a blog published by Umicore. For more information, please visit www.pmc.umicore.com

ASAP’s – 2019 – Week 43-46

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A Gentler Touch: Synthesis of Modern Ruthenium Olefin Metathesis Catalysts Sustained by Mechanical Force Nirmalya Mukherjee, Anna Marczyk, Grzegorz Szczepaniak, Adrian Sytniczuk, Anna Kajetanowicz, and Karol Grela* ChemCatChem 2019 ASAP This … [Continue reading]

ASAP’s – 2019 – Week 41-42

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Fluoro-imidazopyridinylidene Ruthenium Catalysts for Cross Metathesis with Ethylene Seunghwan Byun, Huiyeong Seo, Jun-Ho Choi, Ji Yeon Ryu, Junseong Lee, Won-jin Chung,* and Sukwon Hong* Organometallics 2019 ASAP Synthetic mimics of … [Continue reading]

ASAP’s – 2019 – Week 39-40

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A Divergent Synthetic Route to the Vallesamidine, Strempeliopine and Schizozygine Alkaloids: Total Synthesis of (+)-Vallesamidine and (+)-14,15-Dehydrostrempeliopine Xiangyu Zhang and James. C. Anderson* Angew Chem Int Ed 2019 … [Continue reading]

ASAP’s – 2019 – Week 37-38

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“Close-to-Release”: Spontaneous Bioorthogonal Uncaging Resulting from Ring-Closing Metathesis Valerio Sabatino, Johannes G. Rebelein, and Thomas R. Ward* J Am Chem Soc 2019 ASAP A Metathetic Approach to [5/5/6] Aza-Tricyclic Core of … [Continue reading]

ASAP’s – 2019 – Week 36

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Resonance Promoted Ring-Opening Metathesis Polymerization of Twisted Amides Mizhi Xu, Krista K. Bullard, Aja M. Nicely and Will R. Gutekunst* Chem Sci 2019 ASAP Activation of olefin metathesis complexes containing unsymmetrical … [Continue reading]

ASAP’s – 2019 – Week 35

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Catalytic Living Ring Opening Metathesis Polymerisation: The Importance of Ring Strain in Chain Transfer Agents Peng Liu, Mohammad Yasir and Andreas F.M. Kilbinger* Angew Chem Int Ed 2019 ASAP Highly active ruthenium metathesis catalysts … [Continue reading]

ASAP’s – 2019 – Week 33-34

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Ethyl lactate: A green solvent for olefin metathesis Sebastian Planer, Anupam Jana and Karol Grela* ChemSusChem 2019 ASAP Pulsed-addition ring-opening metathesis polymerization with functional enyne reagents Tianqi Zhang and Will R. … [Continue reading]

ASAP’s – 2019 – Week 32

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Photoinitiated Ring-Opening Metathesis Polymerization Wontae Joo, Christopher H. Chen, Jonathan P. Moerdyk, Ryan P. Deschner, Christopher W. Bielawski, Carlton Grant Willson J Polym Sci A 2019 ASAP Engineering of Molecular Geometry in … [Continue reading]

ASAP’s – 2019 – Week 30-31

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Synthesis of N-Sulfonyl- and N-Acylpyrroles via a Ring-Closing Metathesis/Dehydrogenation Tandem Reaction Weiqiang Chen, Yin-Lin Zhang, Hui-Jing Li*, Xiang Nan, Ying Liu, Yan-Chao Wu* Synthesis 2019 ASAP Living β-Selective … [Continue reading]

ASAP’s – 2019 – Week 29

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Ring-Opening Metathesis Polymerization-Induced Self-Assembly (ROMPISA) Spyridon Varlas, Jeffrey C. Foster,* and Rachel K. O’Reilly* Chem Comm 2019 ASAP A highlight of the recent advances in the field of ROMP mediated polymerization-induced … [Continue reading]