All Things Metathesis

ASAP’s – 2021 – Week 25-30

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Louis Monsigny, Jakub Piątkowski, Damian Trzybiński, Krzysztof Woźniak, Tomasz Nienałtowski, Anna Kajetanowicz,* and Karol Grela*
Adv Synth Catal 2021 ASAP

Near-Infrared Emitting Boron Difluoride Curcuminoid-Based Polymers Exhibiting Thermally Activated Delayed Fluorescence as Biological Imaging Probes
Nathan R. Paisley, Sarah V. Halldorson, Michael V. Tran, Rupsa Gupta, Saeid Kamal, W.
Russ Algar,* and Zachary M. Hudson*
Angew Chem Int Ed 2021 ASAP

Continuous Flow Z-stereoselective Olefin Metathesis: Development and Applications in the Synthesis of Pheromones and Macrocyclic Odorant Molecules
Jennifer Morvan, Tom McBride, Idriss Curbet, Sophie Colombel-Rouen, Thierry Roisnel, Christophe Crévisy, Duncan L. Browne* and Marc Mauduit*
Angew Chem Int Ed 2021 ASAP

Neutral Unsymmetrical Coordinated Cyclophane Polymerization Catalysts
Eva Schiebel, Maria Voccia, Laura Falivene, Inigo Göttker-Schnetmann, Lucia Caporaso,* and Stefan Mecking*
Angew Chem Int Ed 2021 ASAP

Total Synthesis of (+)-3-Deoxyfortalpinoid F, (+)-Fortalpinoid A, and (+)-Cephinoid H
Zhiqiang Ren, Zhongliu Sun, Yifei Li, Xin Fan, Mingda Dai, Yunxia Wang, and Xiangdong Hu*
Angew Chem Int Ed 2021 ASAP

An Ortho-Tetraphenylene-Based «Geländer»-Architecture Consisting Exclusively of 52 sp2 Hybridized C-Atoms
Hervé Dekkiche, Juraj Malinčik, Alessandro Prescimone, Daniel Häussinger and Marcel Mayor*
Chem Eur J 2021 ASAP

Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium-Carbene Catalysts
Daniel L. Nascimento, Marco Foscato, Giovanni Occhipinti, Vidar R. Jensen,* and Deryn E. Fogg*
J Am Chem Soc 2021 ASAP

Ring Opening Metathesis Polymerization of Cyclic Allenes
Geonhui Park and Christopher W. Bielawski*
Macromolecules 2021 ASAP

Olefin metathesis-based chemically recyclable polymers enabled by fused-ring monomers
Devavrat Sathe, Junfeng Zhou, Hanlin Chen, Hsin-Wei Su, Wei Xie, Tze-Gang Hsu,
Briana R. Schrage, Travis Smith, Christopher J. Ziegler and Junpeng Wang
Nature Chem 2021 13 743-750

All Things Metathesis is a blog published by Umicore. For more information, please visit www.pmc.umicore.com

ASAP’s – 2021 – Week 20-24

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Ring-Opening Metathesis Polymerization of δ-Pinene: Well-Defined Polyolefins from Pine Sap Mark R. Yarolimek, Heather R. Bookbinder, Brianna M. Coia, and Justin G. Kennemur* ACS Macro Lett 2021 10 760-766 Nitro and Other Electron … [Continue reading]

ASAP’s – 2021 – Week 17-19

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Engineering a Metathesis-Catalyzing Artificial Metalloenzyme Based on HaloTag Sandro Fischer, Thomas R. Ward,* and Alexandria D. Liang* ACS Catal 2021 11 6343-6347 Fatty Acids and their Derivatives as Renewable Platform Molecules for the … [Continue reading]

ASAP’s – 2021 – Week 15-16

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Total Synthesis of Haliclonin A Yuan Jin, Kensuke Orihara, Fumiki Kawagishi, Tatsuya Toma, Tohru Fukuyama, and Satoshi Yokoshima* Angew Chem Int Ed 2021 60 9666–9671 Light-Driven gem-Hydrogenation: An Orthogonal Entry into “Second … [Continue reading]

ASAP’s – 2021 – Week 08-14

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Fatty Acids and their Derivatives as Renewable Platform Molecules for the Chemical Industry Ursula Biermann, Uwe T. Bornscheuer, Ivo Feussner, Michael A. R. Meier,* Jürgen O. Metzger Angew Chem Int Ed 2021 ASAP Section 3.2.6 of this review … [Continue reading]

ASAP’s – 2021 – Week 02-07

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Cyclic(Alkyl)(amino)carbenes (CAACs) in Ruthenium Olefin Metathesis Jennifer Morvan, Marc Mauduit,* Guy Bertrand,* and Rodolphe Jazzar* ACS Catal 2021 11 1714-1748 Recent Developments in Z-Selective Olefin Metathesis Reactions by … [Continue reading]

ASAP’s – 2020 – Week 47-49

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4-Methyltetrahydropyran as a Convenient Alternative Solvent for Olefin Metathesis Reaction: Model Studies and Medicinal Chemistry Applications Tomasz Nienałtowski, Paweł Krzesiński, Marcel E. Baumert, Aleksandra Skoczeń, Ewa … [Continue reading]

ASAP’s – 2020 – Week 40-46

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Light-Activated Olefin Metathesis: Catalyst Development, Synthesis, and Applications Or Eivgi, Ravindra S. Phatake, Noy B. Nechmad, and N. Gabriel Lemcoff* Acc Chem Res 2020 53 10 2456-2471 Two-Step Divergent Synthesis of Monodisperse … [Continue reading]

ASAP’s – 2020 – Week 35-39

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An RCM-Based Total Synthesis of the Antibiotic Disciformycin B Philipp Waser and Karl-Heinz Altmann* Angew Chem Int Ed 2020 ASAP Efficient Synthesis of Geminal-Dialkyl Dienes for Olefin Metathesis Polymerization William J. Wolf, Jiaming … [Continue reading]

ASAP’s – 2020 – Week 33-34

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Nitro and Other Electron Withdrawing Group-Activated Ruthenium Catalysts for Olefin Metathesis Reaction Anna Kajetanowicz,* and Karol Grela* Angew Chem Int Ed 2020 ASAP This review details the development and diverse applications of electron … [Continue reading]